Testing for alcohols, aldehydes, alkenes and carboxylic acids

 

Functional group Reagent Result
Alkene Bromine water Orange colour decolourises
Aldehyde Fehling’s solution Blue solution to red precipitate
Aldehyde Tollen’s reagent Silver mirror formed
Carboxylic acid Sodium carbonate / sodium hydrogencarbonate Effervescence, CO2 made
10 and 20 alcohol, and aldehyde Sodium dichromate and sulphuric acid Orange to green colour change
Chloroalkane Warm with silver nitrate Slow formation of white precipitate (AgCl)
Bromoalkane Warm with silver nitrate Slow formation of cream precipitate (AgBr)
Iodoalkane Warm with silver nitrate Slow formation of pale yellow precipitate (AgI)
Acyl chloride Silver nitrate Vigorous reaction, steamy fumes of HCl, rapid production of white precipitate (AgCl)

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